The seven-year deal certainly puts Chelsea in a position of strength which had been lacking with outgoing Courtois.
Colombia centre-back Mina would be signing on a permanent deal for a fee of around £27m while Portugal global Gomes would move on a season-long loan for a fee of around £2m.
Athletic confirmed on Wednesday that the 23-year-old's release clause of 80million euros (£71m) was activated and his contract terminated, although made no mention of Chelsea.
Arrizabalaga becomes the most expensive goalkeeper in soccer history, ahead of Liverpool's Alisson, who moved from AS Roma for €75 million earlier in the transfer window.
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"I am very happy to continue in what I consider my home", Kepa stated at the time.
He replaced Belgian global Thibaut Courtois who was sold to Real Madrid after pleading to be reunited with his family. "I need to do my best to prove myself".
"I think we all know that, when you're a kid, there's always a club that really makes you sit up and take notice".
A video on Real Madrid's official Twitter feed showed Courtois signing his contract alongside club president Florentino Perez.
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While the deadline for Premier League transfers closed on Thursday evening, clubs in Spain are still free to complete deals until the end of August.
'It's a very important decision for me, for my career, and also for my personal life.
Kepa made the Athletic number-one spot his own after returning from a loan spell with Real Valladolid at the start of the 2016-17 campaign.
He's not wrong. Kovacic is likely to take game time away from encouraging youngsters such as Ruben Loftus-Cheek.
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